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Rapid, non-destructive characterization of molecular level chemistry for organic matter (OM) is experimentally challenging. Raman spectroscopy is one of the most widely used techniques for non-destructive chemical characterization, although it currently does not provide detailed identification of molecular components in OM, due to the combination of diffraction-limited spatial resolution and poor...
The evolution of the electronic absorption edge of type I, II and III kerogen is studied by diffuse reflectance UV–Visible absorption spectroscopy. The functional form of the electronic absorption edge for all kerogens measured is in excellent agreement with the “Urbach tail” phenomenology. The Urbach decay width extracted from the exponential fit within the visible range is strongly correlated with...
We report the transformation of hydrophilic graphene oxide (GO) sheets into superhydrophobic nanomaterial by direct esterification with epoxy-functionalized polyhedral oligomeric silsesquioxane (ePOSS). The covalently functionalized GO–ePOSS composite shows superhydrophobicity with a water/air contact angle of ∼145°. The highest dispersion limits for GO in selected organic solvents are obtained in...
The growth of carbon nanotubes (CNTs) on graphene quantum dot surface has been explored using acetylene as the carbon source in a catalyst free chemical vapor deposition process. Dynamic studies were conducted to observe the CNT growth. The obtained nanotubes have a diameter distribution of 10–30nm and show medium graphitic quality. Transmission electron microscopy observations and dynamic studies...
Surface compression is a phenomenon in which strong solid–fluid interactions compress the adsorbate molecules on a surface to a point that lateral repulsion forces appear. In this work, this phenomenon was studied for high pressure adsorption of a collection of light gases on polyfurfuryl alcohol (PFA)-derived carbons. The carbons were mostly microporous with mean pore sizes ranging from 5 to 8Å....
The catalytic dissociation of hydrogen molecules by metal nanoparticles and spillover of atomic hydrogen onto various supports is a well-established phenomenon in catalysis. However, the mechanisms by which metal catalyst nanoparticles can assist in enhanced hydrogen storage on high-surface area supports are still under debate. Experimental measurements of metal-assisted hydrogen storage have been...
Ordered microporous carbons containing dispersed platinum nanoparticles were fabricated and chosen as suitable models to investigate micro-structure development and hydrogen transport properties of zeolite-templated carbons. X-ray photoelectron spectroscopy analysis revealed that the enhanced heat of adsorption is related to the narrow micro-channels templated from the zeolite and the presence of...
A carbon black derivative was prepared through a three-step procedure involving sonication-assisted oxidation, covalent grafting by a charged polysiloxane quaternary ammonium salt and ion exchange with a poly(ethylene) glycol-functionalized sulfonate salt. Such surface-functionalized carbon black can behave as a liquid at room temperature in the absence of any solvent. Transmission electron microscopy...
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