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The reactions of the bis(η 5 -cyclopentadienyl)methylzirconium cation (1) with four imines have been studied in the gas phase by Fourier transform ion cyclotron resonance mass spectrometry. Reactivity of the bis(η 5 -cyclopentadienyl)methylzirconium cation is governed by the availability of a labile hydrogen in the corresponding imine. The products observed differ from those that might...
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