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We report new analogs of 1α,25-dihydroxyvitamin D 3 (1) in three categories. First, design and synthesis of ligands for a mutant vitamin D receptor (VDR)(Arg274Leu), which possess proper functional groups at both C1α and C2α positions of 1 to study the biological activity of the mutant VDR. Among our synthetic analogs, 1α-methyl-2α-(3-hydroxypropyl)-25-hydroxyvitamin D 3 (8) showed...
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