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Bis(2-pyridyl)diselenoether with the general formula (2-PySe)2(CH2) (L) reacts with Ph3PAuCl and [(dpph)(AuCl)2] dpph=1,6-bis(diphenylphosphino)hexane to produce the respective complexes [(L)Au2(PPh3)2](PF6)2 (1) and [(L)(dpph)Au2(PF6)2]n (2). These complexes were isolated in crystalline form and studied using spectroscopic and X-ray diffraction techniques. The coordination of the ligand (2-PySe)2...
Novel gold(I) complexes based on thiocarbamoyl-pyrazoline ligands were synthetized for the first time and their structural/photophysical properties were determined. Two new monocationic complexes of the type [(Ph) 3 PAu(L)]PF 6 (L=1-thiocarbamoyl-5-(4-halophenyl)-3-phenyl-pyrazoline) were prepared by reacting (Ph) 3 PAuCl and ligands in the presence of KPF 6 in a 1:1:1...
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