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CYP11A1 hydroxylates the side chain of vitamin D3 (D3) in a sequential fashion [D3→20S(OH)D3→20,23(OH) 2 D3→17,20,23(OH) 3 D3], in an alternative to the classical pathway of activation [D3→25(OH)D3→1,25(OH) 2 D3]. The products/intermediates of the pathway can be further modified by the action of CYP27B1. The CYP11A1-derived products are biologically active with functions determined...
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