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The porous networks of [Cu 2 (malonato) 2 (bipy)(H 2 O) 2 ].H 2 O (I) and [Cd(malonato)(py)(H 2 O)] (II) were co-assembled by rigid 4,4'-bipyridine or pyridine and the flexible malonate ion. In the network of compound I, 4,4'-bipy acts as a bone, separating and supporting the flexible malonate-Cu units to form a nearly strain-free square framework and...
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