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The complexes Cp*Rh(beapy)Cl (5) and Cp*Ir(beapy)Cl (6) were synthesized by reaction of [Cp*MCl 2 ] 2 (M=Rh, Ir) and the deprotonated ligand Hbeapy, the condensation product of benzylamine and 2-pyrrolcarbaldehyde. In each case two enantiomers (S M ) and (R M ) arise, differing only in the metal chirality. The CH 2 group of the benzyl substituent in the ligand...
Ortho-metalated derivatives of the optically active ligand (S)-(-)-N,N-dimethyl(1-phenylethyl)amine (LL*-H) react with [(η 6 -p-cymene)MCl 2 ] 2 (M=Ru, Os) to give the half-sandwich complexes [(η 6 -p-cymene)Ru(LL*)Cl] (1a,b) and [(η 6 -p-cymene)Os(LL*)Cl] (2a,b). In both cases two diastereomers (R M ,S C ) and (S M ,S C ) arise...
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