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The vibrational spectra of Eu[Co(CN) 6 ]·4H 2 O and luminescence spectra of Eu 3+ in this compound, using 355nm excitation at temperatures down to 10K, have been assigned. A clear distinction is made between the n=5 and 4 members of the Ln[M(CN) 6 ]·nH 2 O series from the vibrational spectra. The electronic spectra show prominent vibronic structures, particularly...
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