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The electrochemical behavior of samarium ions in LiF-CaF2 melts at tungsten electrodes is investigated by cyclic voltammetry and square wave voltammetry. The electrochemical reduction of Sm(III) into Sm(II) according to Eq. (1) is reversible within 900mV/s.Sm3++e−→Sm2+(1)The reduction process for Sm(II) to Sm cannot be observed due to a more negative potential than that of Li(I) ions. Cyclic voltammograms...
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