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Amphiphilic triblock copolymer of poly(ethylene glycol)-block-poly(dimethylaminoethyl methacrylate)-block-poly(ε-caprolatone) (PEG-PDMA-PCL) was synthesized using a one-pot sequential oxyanionic polymerization of DMA and ε-CL, associated with a PEG-O − K + macroinitiator. The pH-responsive micellization behavior of the copolymer was studied using dynamic light scattering (DLS), steady–state...
An amphiphilic triblock poly (ethylene glycol)–block-poly (acrylate acid)–block-poly (ε-caprolactone) (PEG–PAA–PCL) copolymer was synthesized by sequential anionic polymerization. By comparing with diblock copolymer poly (acrylic acid)–block-poly (ε-caprolactone) (PAA–PCL), the triblock copolymer (PEG–PAA–PCL) micelle has core–shell–corona structure, which possesses better dispersion, could be a good...
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