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For tetraphenylporphyrin derivatives substituted with four fluorocarbon chains (TFPP), monolayers on the water surface were studied with the Brewster angle microscope together with pressure–area curves. It was found that heterogeneous aggregated structures of the monolayers were dependent upon the chain length of fluorocarbons, the metal-free or Mn-TFPP, and the periods after spreading. Polarized...
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