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We have synthesized the multicomponent species N(ph)5A, where a 1-naphthyl (N) and a 9-anthryl (A) units are connected by a 1,4-pentaphenylene rod-like spacer ((ph)5). The overall length of the compound is 3.1 nm and the center-to-center distance between the naphthyl and anthryl units is 2.6 nm. The absorption and emission spectra of N(ph)5A have been investigated in cyclohexane solution at 293 K...
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