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Partitioning coefficients into differing acyclic aliphatic alcohols can be described by the linear solvation energy relationship (LSER) equations with 6 fitting parameters to the accuracy of 0.19–0.20log units. If 6 more fitting parameters are added to account for the slight dependency of the partitioning coefficients on the number of carbon atoms of alcohols, the accuracy improves to 0.15–0.16, comparable...
Solute descriptors of linear solvation energy relationship (LSER) for dialkyl ethers were examined as a means for improving predictions of their fate and behavior in the environment. LSER solute descriptors consist of the excess molar refraction, the polarizability/dipolarity parameter, the effective hydrogen (H)-bond acidity/basicity, McGowan's characteristic volume and the hexadecane–air partitioning...
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