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5‐hydroxylmethylfurfural (HMF) is a bio‐based chemical that can be prepared from natural abundant glucose by using combined Brønsted–Lewis acid catalysts. In this work, Al3+ catalytic site has been grafted on Brønsted metal–organic frameworks (MOFs) to enhance Brønsted–Lewis acidity of MOF catalysts for a one‐pot glucose‐to‐HMF transformation. The uniform porous structure of zirconium‐based MOFs allows...
5‐hydroxylmethylfurfural (HMF) is a value‐added chemical obtained from sugars including glucose. In article number 2006541, Satoshi Horike, Kanokwan Kongpatpanich, and co‐workers design a metal–organic framework (MOF) catalyst for glucose‐to‐HMF transformation by incorporation of Lewis Al3+ site to Brønsted sulfonated MOFs. The local structure of acid sites is elucidated by XANES and DFT calculations...
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