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Hemicryptophanes are covalent molecular cages, constructed from a cyclotriveratrylene-based host unit and a functional unit linked by covalent spacers, which have been designed to accommodate endohedral functionalities in the cavity. In this study, the synthesis and characterization of the rigid, biphenyl-linked hemicryptophane 1 were investigated by NMR, ESI-MS, and X-ray crystallography. The structure...
Hemicryptophanes have been designed to include endohedral functionalities in the cavity, giving molecular receptors and catalysts. In this study, a tri-aromatic amide hemicryptophane was synthesized. The host–guest interactions with various types of tetraalkylammonium salts were investigated. The structure of the partial inclusion complex in which an acetylcholine molecule was encapsulated within...
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