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The hydrothermal reaction of Zn(NO 3 ) 2 ·6H 2 O, bpp and NH 4 VO 3 in water at 140°C for 80h yields an unprecedented chiral three-dimensional vanadium oxide complex, [Zn(bpp)V 2 O 6 ] (1). The structure of 1 consists of wave-like two-dimensional networks, linked through {ZnO 2 N 2 } building blocks and bpp ligands into a three-dimensional...
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