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An aluminum and fluorine enriched anodic film was fabricated on Ti50Al by anodizing in ionic liquid (IL) 1-butyl-3-methylimidazolium hexafluorophosphate (BmimPF6). The formation mechanism and the exact role of fluorine for the generation of this anodic film were deeply investigated. Results show that the trace amounts of residual water in the ionic liquid were responsible for the generation of oxygen...
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