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The reactions of a self-assembled silver(I) coordination polymer, [Ag 2 {μ-Pr i N(PPh 2 ) 2 }(μ-NO 3 ) 2 ] n (1) with various bidentate N-donor ligands such as DABCO, 2,2′-bipyridyl and 1,10-phenanthroline yield 1-D helices or π–π stacked polymers, depending on the chelate vector of the N-donor ligand. The molecular structures of the resultant...
Mononuclear, binuclear and trinuclear silver(I) complexes were obtained unexpectedly while probing the reactivity of diphosphazane ligands of the type X 2 PN(Pr i )PXY towards the ruthenium-based precursor Ru(bipy) 2 Cl 2 ·2H 2 O, in the presence of a silver salt as a chloride scavenger. Subsequently, the reactions of AgX [X=Cl,NO 3 or CF 3 SO...
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