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The kinetics and mechanism of oxidation of aspartic acid by the bis(hydrogen periodato) complex of Cu(III), [Cu(HIO6)2]5−, is studied in an alkaline medium. The reaction rate is first order with respect to Cu(III) and fractional order with respect to aspartic acid. The value of the observed rate constant is found to decrease with the increase in concentrations of either OH− or IO4−. There is a positive...
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