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The novel pincer ligand 2,2'-bis(diphenylphosphino)diphenylamine (1) has been synthesized by treatment of 2,2'-dibromodiphenylamine with n-butyl lithium and subsequent reaction with diphenylchlorophosphine. When ligand 1 is treated with RhCl 3 hydrate the dinuclear complex 1a forms which can be converted into the square planar carbonyl complex 1c upon reduction with Na/Hg in the presence of...
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