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Scanning electrochemical microscopy (SECM) is employed to investigate the effect of solution viscosity on the rate constants of electron transfer (ET) reaction between potassium ferricyanide in water and 7,7,8,8-tetracyanoquinodimethane (TCNQ) in 1,2-dichloroethane. Either tetrabutylammonium (TBA + ) or ClO 4- is chosen as the common ion in both phases to control the interfacial...
The study of interfacial electron transfer (ET) reaction between ferricinium (Fc+) producedin situ in 1,2-dichloroethane (DCE) and ferrocyanide in ice matrix under low temperatures by the scanning electrochemical microscopy (SECM) is reported. Tetrabutylammonium (TBA+) is used as the common ion (potential-determining ion) in both phases to control the interfacial potential difference. The potential...
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