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RAFT polymerization of N,N-diethylacrylamide was achieved using three different chain transfer agents bringing cyanoisopropyl, cumyl, or tert-butyl R groups, in different solvents (dioxane, toluene), or in bulk. Reactions were controlled and allowed the synthesis of poly(N,N-diethylacrylamide) with targeted molecular weights. Best results were obtained with cyanoisopropyl dithiobenzoate at 80 °C in...
The paper describes the optimization of copper(I) mediated living radical polymerization of N-hydroxysuccinimide methacrylate to achieve AB block copoly(acryl amides) offering a route to polymers with potential biomedical applications. Polymerization of N-hydroxysuccinimide methacrylate was carried out using copper(I) bromide/N-(n-propyl)-2-pyridylmethanimine catalyst with ethyl-2-bromoisobutyrate...
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