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A phase diagram of a dodecyltrimethylammonium bromide (DTAB)–didodecyldimethylammonium bromide (DDAB) system was obtained by a combination of two fluorescence probes, auramine and pyrene. In the DTAB-rich region, a vesicle was formed at first, and then a vesicle–micelle transition occurred at a higher concentration, near the critical micelle concentration of DTAB. On the other hand, in the region...