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Summary. Straightforward 31P MAS investigations were carried out in the solid state on a series of [Pd2X2(dppm)2] (X=Cl, Br, I) complexes in order to study the effects that ring distortion, conformations, and crystal packing have on the solid-state spectra of these molecules and also to get experimental values for certain scalar couplings (e.g. two-bond trans P–Pd–P) normally not available from...
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