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Two commercial metal-organic frameworks, Cu 3 (BTC) 2 and Fe(BTC), have been selected to compare the adsorption parameters obtained on these materials by two different techniques: immersion calorimetry and inverse gas chromatography (IGC), in order to find a relationship between thermodynamic parameters obtained by so different techniques. From comparison between the enthalpy of adsorption...
Adsorption properties (enthalpy of adsorption, free energy of adsorption as well as the dispersive and specific components of free energy of adsorption) of several hydrocarbons on zeolites 13X and 5A have been evaluated by inverse gas chromatography (IGC). A parallelism between the effects of the molecular diameter on the enthalpy of immersion and the parameter of specific interaction was found for...
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