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A new heterometallacrown coordination polymer [K 2 Cu(NPA) 2 (H 2 O) 4 ] n (where H 2 NPA=3-nitro-phthalic acid) has been synthesized and it’s crystal structure has been elucidated. In the complex, the o-phthalate group coordinates to metal atoms behaving as both tetradentate and heptadentate coordination, the modes of which have been found for the first...
A thiadiazole derivative, 5-benzylsulfanyl-2-amino-1,3,4-thiadiazole (BSATZ) was prepared. The single crystal structure of BSATZ was determined by X-ray diffraction and the thermal behavior of BSATZ in nitrogen was studied by TG and DSC. Based on the results of thermal analysis, the thermal decomposition mechanism of BSATZ in the temperature range of 100–400°C was derived and the kinetic parameters...
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