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Florierendes Fluor: Die Umsetzung eines α‐Trifluormethylallylbenzoats mit Alkoholen in Gegenwart eines ortho‐cyclometallierten Iridium‐Katalysators führt zur Bildung von Aldehyd‐Allyliridium‐Intermediaten, aus denen die enantiomerenangereicherten Produkte einer anti‐α‐Trifluormethylallylierung entstehen. Ein identischer Satz von Produkten wird ausgehend von Aldehyden erhalten, wenn ähnliche Transferhydrierungsbedingungen...
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