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This work presents an investigation of the role of the nitrogen flow rate on the composition, structure and ionic conductivity of thin films prepared by reactive radio-frequency (rf) sputtering of lithium metaborate targets. It was found that sputtering at constant nitrogen pressure but with increasing nitrogen flow rate leads to thin films with significantly increased nitrogen content. The effect...
AgI-doped superionic borate glasses xAgI-(1-x)[Ag 2 O-nB 2 O 3 ] (n=2, 0.5) in bulk and thin film forms were studied by infrared specular reflectance and transmission spectroscopy. The short-range order structure of the network was found to be directly affected by AgI, and this was accounted for by isomerization and disproportionation reactions between triangular and tetrahedral...
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