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The comparison of Fe3BO5 and Fe2MnBO5 reveals that the 2Fe2+: Fe3+ charge ordering of the former is suppressed in the latter. Spin dynamics probed by ac susceptibility are strongly affected by the substitution, inducing superparamagnetism at low temperature in Fe2MnBO5. Interestingly, for both oxyborates, glassiness is observed in the dielectric properties at low temperature, but only Fe3BO5 shows...
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