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Using thermal desorption spectroscopy (TDS) we have determined the adsorption enthalpies of NO and CO on a NiO(100) surface obtained by cleavage of a NiO single crystal rod under ultra-high vacuum (UHV) conditions. The TDS data have been evaluated using the leading edge method and complete analysis, yielding values of 0.30±0.04 and 0.57±0.04eV for the heats of adsorption of CO and NO, respectively,...
The results of angular resolved photoemission and thermal desorption spectroscopy investigations of the adsorption of CO and NO on a WC(0001) single crystal surface are reported. Both molecules are stable only at low temperature. Similar to the case of adsorption on many transition metals, CO is co-ordinated to the surface via its carbon end, standing upright on the surface. Upon warming up, complete...
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