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The adsorption of CO molecules on the Cr-terminated (0001) surface plane of Cr 2 O 3 is studied theoretically by means of quantum chemical cluster calculations and experimentally by thermal desorption spectroscopy and infrared reflection absorption spectroscopy. The combination of these approaches yields a detailed picture of the CO/Cr 2 O 3 (0001) adsorption. In the...
Rh deposits in a wide range of metal exposures have been grown on a thin, well-ordered alumina film under ultra-high vacuum conditions. Their morphologies range from individual Rh particles with sizes below ten atoms to closed metal films, as determined by scanning tunneling microscopy (STM). CO chemisorption on these deposits has been studied by infrared reflection absorption spectroscopy (IRAS)...
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