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Porous carbon materials doped with nano-sized transition metal carbides and/or metal-nitrogen coordinative sites are promising oxygen reduction electrocatalysts. The doping of such functionalities in carbon materials with desirable concentration, ultra-small size and stable configuration is still a challenge. In this paper, by grinding and pyrolyzing solid mixtures of an amino acid, an iron salt,...
Monolithic porous carbon (MPC) was synthesized by a templating method using Na 2 CO 3 as template, novolac-type phenolic resin as carbon precursor and hexamethylenetetramine as hardening agent. The template, carbon precursor and hardening agent were mechanically mixed in a grinding machine, hardened at 150°C, crushed into fine particles, compacted into a disc, carbonized at 800°C and...
We used a two-layer structure consisting of polyethylene terephthalate (PET) and silicone to transfer graphene grown by chemical vapor deposition onto various rigid and flexible substrates through dispersive adhesion. It only takes a few seconds to transfer graphene from PET/silicone to the target substrates at ambient conditions. And the recycling of the PET/silicone decreases the production cost...
We report the effects of oxygen doping on the electrical properties of defective metallic and semiconducting single-walled carbon nanotube bundles. Carbon vacancies are generated by electron beam knock-out process. The carbon nanotube bundles are placed on top of suspended electrodes produced on a through-hole chip. This allows a physical correlation to be established for transmission electron microscopy...
The spin orbit interaction in a carbon nanotube is probed by Kondo resonance. Spin orbit interaction lifts level degeneracy and leads to additional satellite current peaks along with the zero-bias Kondo resonance peak. From the positions of satellite peaks, the spin–orbit interaction energy Δ so is determined to be 0.38meV. In the presence of a parallel magnetic field, the satellite peaks...
Carbon coils of micrometer to nanometer wire diameter were grown bi-directionally by catalyst-assisted chemical vapor deposition. Electron microscope images showed the highly disordered structure of the carbon coils. Chemical compositions of the coils were identified with elemental analysis, atmospheric pressure-laser desorption ionization-Fourier-transform ion cyclotron resonance-mass spectroscopy...
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