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Recently, we developed new equations of state for the freely jointed hard sphere chain fluids, which are based on the thermodynamic perturbation theory (TPT) of sequential polymerization. The equations of state use the contact values of the radial distribution function (RDF) for monomer-dimer mixtures, which is derived from the multidensity Ornstein-Zernike (MOZ) theory. In this work, we extend one...
New equations of state for the freely jointed hard sphere chain fluids are developed. The equations of state are based on Wertheim's thermodynamic perturbation theory or the statistical associating fluid theory. In developing the new equations of state we use the contact values of the radial distribution functions (RDF) of equimolar mixtures of monomer and dimer fluids as an intermediate reference...
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