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The reaction between NiCl 2 , NaSPh and NaEH (E = S,Se) in a mixture of acetonitrile and acetone gave trinuclear clusters [Ni 3 (μ-E)(μ-SPh) 3 (SPh) 3 ] 2- (E = S,Se) and the previously characterized mononuclear complex [Ni(SPh) 4 ] 2- . The X-ray structures of the trinuclear clusters are similar to each other except for the Ni ...
A TPA variant with replacement of amino acids is provided. In a typical embodiment, the variant has an amino acid sequence with replacement of the amino acid group consisting of asparagine at the 37th position, serine at the 38th position, glycine at the 39th position, arginine at the 40th position, alanine at the 41st position, and glutamine at the 42nd position from the N-terminus of the amino...
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