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Abstract. The Lny-xCa2-xMnO4 series, with a K2NiF4 structure, has been studied by neutron powder diffraction and electron microscopy in connection with the magnetic and transport properties. We report here the results of the structural and magnetic study of two compounds, Pr0.25Ca1.75MnO4 and Ho0.08Ca1.92MnO4, for which the Mn valency is 3.75 and 3.92 respectively and consequently that show different...
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