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Three zinc-tetraarylporphyrins were prepared in order to investigate the effects of systematic meso-π-extension on the redox behaviors and interfacial electron transfer kinetics. The meso-π-extension increased at a 2n pattern, where 2n was the benzene ring number in an aryl group and the aryl group represented phenyl, naphthyl and pyrenyl group, respectively. The structures of zinc-tetraarylporphyrins...
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