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A novel phosphorus-based alloy composite, Sb–CuP2–C, is synthesized by a simple two-step high-energy ball milling (HEBM) method and used as an anode material for sodium-ion batteries. The HEBM process with Sb, Cu, P, and C generates Sb and CuP2 phases instead of forming Cu2Sb and P owing to the differences in binding energy among the elements, which is confirmed by density functional theory. The as-prepared...
We present a facile approach to making Al-Sb, carbon-modified (Al-Sb-C) nanocomposites for use as new anode materials in lithium-ion batteries (LIB). Alloying is achieved by one step synthesis using high energy mechanical milling (HEMM), producing nanometer-sized alloy particles of Sb-AlxCy-C. Based on electrochemical analyses, we determined that Sb acts as an active material, and both Al and carbon...
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