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Multicomponent alkene 1,2‐dicarbofunctionalizations (DCFs) have emerged as a powerful strategy to rapidly incorporate both two carbon subunits across one C—C double bond in one step for enhancing molecular complexity and diversity. To the best of our knowledge, there is only one report on photoredox‐catalyzed three‐component DCFs with malonates through the radical−radical cross‐coupling, while photoredox‐catalyzed...