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While chain‐walking stimulates wide interest in both polymerization and organic synthesis, site‐ and stereoselective control of chain‐walking on rings is still a challenging task in the realm of organometallic catalysis. Inspired by a controllable chain‐walking on cyclohexane rings in olefin polymerization, we have developed a set of chain‐walking carboborations of cyclohexenes based on nickel catalysis...
While chain‐walking stimulates wide interest in both polymerization and organic synthesis, site‐ and stereoselective control of chain‐walking on rings is still a challenging task in the realm of organometallic catalysis. Inspired by a controllable chain‐walking on cyclohexane rings in olefin polymerization, we have developed a set of chain‐walking carboborations of cyclohexenes based on nickel catalysis...