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The valence electron concentration (VEC) is an important physical factor for phase formation. A high VEC is conducive to forming an FCC phase and improving an alloy's ductility, while a low VEC is beneficial in forming a BCC phase that improves an alloy's strength. This is demonstrated for two HEAs, CoCrCuFeNi (FCC) and AlCoCrFeNi (BCC), that were designed as matrix alloys, where Ni and Mo are alloyed...
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