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We have developed various techniques to count catalytic sites of Au/TiO 2 catalysts for the water–gas shift (WGS) reaction. Addition of Br in an amount that is only 16% of the moles of the surface Au on a 2.3wt.%Au/TiO 2 catalyst decreases the majority of its WGS reaction rate per total mole of Au but does not result in an appreciable change in the average Au particle size, Au particle...
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