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•The synthesis of B-vinylcarboranes from iodocarboranes and vinylmagnesium bromide in the presence of Pd catalysts was revised.•Vinyl group of the 9-vinyl-1,2-dicarba-closo-dodecaborane undergoes a variety of organic transformations such as electrophilic addition, oxidation, radical addition etc. to form corresponding closo-carborane products with modified side chain.•Bis(dicarbollyl) complexes of...
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