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Buckybowls are fascinating components of supramolecular assemblies owing to their unique bowl‐shaped π‐surfaces. Herein we present a protocol for the functionalization of a sulfur‐doped buckybowl, trithiasumanene, via a brominated intermediate, from which thiolated trithiasumanenes were derived. The curved surface and electron‐donating properties of thiolated trithiasumanenes promote their ready assembly...
Experimental and theoretical studies focusing on the formation of carbon clusters are described. In the experiment on discharge in liquid chloroform, a series of perchlorinated fragments of C60 was synthesized and a scarce amount of C60 was detected. In the laser vaporization experiments, it was found that the production of C 60+ and other fullerene ions could be promoted by doping chlorine-containing...
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