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While the N‐trifluoromethylation of cyclic ureas is of interest for the potential to fundamentally change the properties of these biologically relevant moieties, the single synthetic procedure known to date describing their access only gives 4,4‐disubstituted or fused aromatic cyclic N‐CF3 urea derivatives. We herein report an alternative approach to unleash access to the 4‐monosubstituted imidazolidinone...
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