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In this report, hierarchical self-organization of poly(tert-butyl acrylate) (PtBA) brush- and mixed PtBA/polystyrene (PS) brush-grafted silica nanoparticles (NPs) in PtBA-b-PS block copolymer and PtBA/PS polymer blend matrices having different molecular weights was investigated using transmission electron microscopy (TEM). Driven by the entropic interactions between the brushes and the polymer matrices...
This article reports reversible changes in surface morphology and surface wettability of mixed poly(methyl methacrylate) (PMMA)/polystyrene (PS) brushes with PS M n slightly lower than that of PMMA in response to combined selective solvent treatments and thermal annealing. The mixed brushes were synthesized from asymmetric difunctional initiator-terminated monolayers by controlled radical...
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