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Glassy Na‐ion solid‐state electrolytes (GNSSEs) are an important group of amorphous SSEs. However, the insufficient ionic conductivity of state‐of‐the‐art GNSSEs at room temperature lessens their promise in the development of all‐solid‐state Na‐ion batteries (ASSNIBs) with high energy density and improved safety. Here we report the discovery of a new sodium superionic glass, 0.5Na2O2‐TaCl5 (NTOC),...
Glassy Na‐ion solid‐state electrolytes (GNSSEs) are an important group of amorphous SSEs. However, the insufficient ionic conductivity of state‐of‐the‐art GNSSEs at room temperature lessens their promise in the development of all‐solid‐state Na‐ion batteries (ASSNIBs) with high energy density and improved safety. Here we report the discovery of a new sodium superionic glass, 0.5Na2O2‐TaCl5 (NTOC),...
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