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Self-assembly schemes provide a simple and tunable approach to creating a myriad of well-defined nanostructures from design of macromolecules in bulk, thin film and solution environments. Here we demonstrated a facile method to construction of tetraphenylethylene nanoparticles (TPE NPs) by decomposition-assembly from pH-responsive and AIE-characteristic vesicles, which were self-assembled by an amphiphilic...
The small-angle neutron scattering (SANS) technique has been used to investigate the structure of dendrimers based on polyhedral oligomeric silsesquioxane (POSS) in solution. Three generations and two distinct terminal groups (either vinyl or polyethylene glycol (PEG) terminal groups) as well as four concentrations for each dendrimer have been measured in deuterated tetrahydrofuran. Two main scattering...
The Biginelli reaction has been utilized as an effective click reaction to collaborate with π–π stacking to prepare carbon nanotube-polymer conjugates. The synthesized polymers are successfully anchored on carbon nanotube surface via ‘grafting to’ strategy, and the obtained carbon nanotube-polymer composites possessing characteristic properties of anchored polymer can be well dispersed in general...
Hollow titania containing multilayer nanofibers was fabricated through the combination of electrospinning with layer-by-layer technique. Two different solvents, methylbenzene and THF were used to remove the template. The morphology of the obtained hollow multilayer nanofibers confirmed that THF is better than methylbenzene. The obtained hollow multilayer fiber has a diameter of about 700nm and its...
Poly(malachite green) films were synthesized electrochemically on the glassy carbon electrode in the potentiodynamic mode. The characterization and growth mechanism of as-prepared films were studied with FT-IR spectroscopy, UV–vis spectroscopy, cyclic voltammetry, chronocoulometry, and electrochemical impedance spectroscopy. Charge transfer and ion transport of poly(malachite green) films were investigated...
In this article, we described the synthesis of comb oligomers having rigid racemic or chiral binaphthyl macrocyclic pendant groups via the free radical polymerization. Oligomers obtained were well characterized by MALDI-TOF-MS, 1 H NMR, FT-IR, UV, CD and SEC. These comb oligomers having macrocyclic pendant groups showed very good solubility in common organic solvents at room temperature. Furthermore,...
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