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Dimeric and trimeric tetrathiafulvalene (TTF) derivatives possessing carbonyl groups in the spacer (1, 2) and dimeric TTF derivatives and tetrathiapentalene (TTP) derivatives possessing ester groups in the spacer (3, 4) have been synthesized. Cyclic voltammogram of 1–3 exhibits two pairs of redox waves. No significant shift of redox potentials was observed as increase of the TTF units. Cyclic voltammogram...
We investigate physical properties of the CT complexes of a new asymmetric (EDOB)(EDT)TTF donor which consists of the parts of BEDO-DBTTF and BEDT-TTF. The conductivities of the CT complexes are measured. The crystal structure of the radical salt [(EDOB)(EDT)TTF] 2 PF 6 is analyzed and the band structure is discussed.
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