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Zirconium phenylphosphonate (ZrPP) films with different crystallite orientations have been fabricated on unmodified and surface-sulfonated polystyrene (PS) substrates by an in situ hydrothermal crystallization method. On the unmodified PS substrate, a monolayer film with the hexagonal ab planes of the ZrPP crystallites parallel to the PS can be obtained by restricting the crystallization time. After...
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