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The diameter of a dispersed‐phase droplet determines the interfacial area in liquid–liquid solvent extraction. Capturing the polydispersity of a liquid–liquid flow is crucial in computational fluid dynamics. In this study, a droplet size probability (DSP) model applied to the Eulerian–Eulerian (E–E) framework is proposed to characterize the droplet size distribution (DSD) at mesoscale. The physical...